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Transition State Geometry and a Polar Effect in the Reactions of Peroxy Radicals with Oxygen-Containing Compounds

โœ Scribed by T.G. Denisova; E.T. Denisov


Book ID
111597199
Publisher
Springer
Year
2004
Tongue
English
Weight
72 KB
Volume
45
Category
Article
ISSN
0023-1584

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The photolysis of 1,1,3,3-tetrafluoroacetone has been reinvestigated as a source of CHFz radicals at temperatures up to 578'K, and the following rate constant ratio was determined for the reactions (8) (7) 2CHF2 -+ CHFzCHFz\* CHFz + CHFzCOCHFz -+ CHzFz + CF~COCHFZ log (k~/k~1'2)(mole-1'zcc1'2sec-1'2