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Reactions of Peroxy Radicals with Hydrocarbons and Alcohols: Transition State Geometry and the Polar Effect

✍ Scribed by T. G. Denisova; N. S. Emel'yanova

Book ID
111548961
Publisher
Springer
Year
2003
Tongue
English
Weight
73 KB
Volume
44
Category
Article
ISSN
0023-1584

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Rate constants and transition-state geom
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✍ Evgeny Denisov; Crissostomos Chatgilialoglu; Aleksander Shestakov; Taisa Denisov πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 149 KB

## Abstract Enthalpy, activation energy, and rate constant of 9 alkyl, 3 acyl, 3 alkoxyl, and 9 peroxyl radicals with alkanethiols, benzenethiol, and L‐cysteine are calculated. The intersection parabolas model is used for activation energy calculations. Depending on the structure of attacking radic