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Transition Metals in the Synthesis and Functionalization of Indoles [New Synthesis Methods (72)]

โœ Scribed by Prof. Louis S. Hegedus


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
1014 KB
Volume
27
Category
Article
ISSN
0044-8249

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Carbonylation of Transition-Metal Carbyn
โœ Dr. Fritz R. Reissl; Dipl.-Chem. Wolfgang Uedelhoven; Dipl.-Chem. Karl Eberl ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 141 KB ๐Ÿ‘ 2 views

**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and โˆ’30ยฐC to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60ยฐC and under 60atm pre