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ChemInform Abstract: New Methods for the Synthesis of Transition-Metal Fullerene Complexes

โœ Scribed by David M. Thompson; Jason McLeod; Michael C. Baird


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
32
Category
Article
ISSN
0931-7597

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Carbonylation of Transition-Metal Carbyn
โœ Dr. Fritz R. Reissl; Dipl.-Chem. Wolfgang Uedelhoven; Dipl.-Chem. Karl Eberl ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 141 KB ๐Ÿ‘ 2 views

**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and โˆ’30ยฐC to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60ยฐC and under 60atm pre