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A New Method for the Preparation of Transition Metal-Carbene Complexes

✍ Scribed by Dr. Wolfgang Anton Herrmann

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
127 KB
Volume
13
Category
Article
ISSN
0044-8249

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Carbonylation of Transition-Metal Carbyn
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✍ Dr. Fritz R. Reissl; Dipl.-Chem. Wolfgang Uedelhoven; Dipl.-Chem. Karl Eberl πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 141 KB πŸ‘ 1 views

**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and βˆ’30Β°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60Β°C and under 60atm pre