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Transition Metals for Organic Synthesis || Manganese(III)-Based Oxidative Free-Radical Cyclizations

โœ Scribed by Beller, M.; Bolm, C.


Book ID
120498860
Publisher
Wiley-VCH Verlag GmbH
Year
2004
Weight
269 KB
Category
Article
ISBN
3527306137

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Manganese (III) based oxidative free-rad
โœ Barry B. Snider; Raju Mohan; Steven A. Kates ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 292 KB

Oxidative c Z clization of 5 with Mn(OAc) \*2H 0 gives mainly the bit clic products 7 On the other and, These data sug est oxidative cyclization if lb and 17 gives mainly t e lactones 18 and Z 20. to form 3, 4, 7, an % a. that oxidation of a monocyclic radical to a cation precedes cyclization Oxid