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Manganese (III) based oxidative free-radical cyclizations. 3. Polycyclization reactions proceeding through secondary radicals.

โœ Scribed by Raju Mohan; Steven A. Kates; Mark A. Dombroski; Barry B. Snider


Book ID
104233407
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
322 KB
Volume
28
Category
Article
ISSN
0040-4039

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Manganese (III) based oxidative free-rad
โœ Barry B. Snider; Raju Mohan; Steven A. Kates ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 292 KB

Oxidative c Z clization of 5 with Mn(OAc) \*2H 0 gives mainly the bit clic products 7 On the other and, These data sug est oxidative cyclization if lb and 17 gives mainly t e lactones 18 and Z 20. to form 3, 4, 7, an % a. that oxidation of a monocyclic radical to a cation precedes cyclization Oxid