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Transition Metal Ions and Amides, VI. Complexation of the neutral and the anionic forms of 3, 7-diazanonanedioic acid diamide and 3, 7-diazanonanedioic acid diethylamide with Cu2+ and Ni2+

✍ Scribed by Thomas A. Kaden; Andreas D. Zuberbühler


Publisher
John Wiley and Sons
Year
1974
Tongue
German
Weight
423 KB
Volume
57
Category
Article
ISSN
0018-019X

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Formation and Dissociation Mechanism of
✍ Andreas D. Zuberbühler; Thomas A. Kaden 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 365 KB

## Abstract The protonation and deprotonation rates of the coordinated amide groups in the Ni^2+^ and Cu^2+^ complexes of 3,7‐diazanonanediamide (DANA) and in the Cu^2+^ complex of 3,7‐diazanonane‐N,N′‐diethylamide (DANEA) have been studied by stopped‐flow techniques. For the interconversion M(H~−2