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Transition Metal Complexes with Bidentate Ligands Spanning trans-Positions. VIII. The reactions of the nucleophile trans-[RuCl(NO)(1)] (1 = 2,11-bis(diphenylphosphinomethyl)benzo[c]-phenanthrene) with carbon monoxide and the phosphite ligand (2) (2 = 1-ethyl-3,5,8-trioxa-4-phosphabicyclo (2.2.2)octane)

✍ Scribed by Rolf Holderegger; Luigi M. Venanzi; Fiorella Bachechi; Pasquale Mura; Luigi Zambonelli

Publisher
John Wiley and Sons
Year
1979
Tongue
German
Weight
540 KB
Volume
62
Category
Article
ISSN
0018-019X

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## Abstract The five‐coordinate mononuclear complexes [M(CO)~3~(**1**)] (M = Fe, Ru; (**1**) = 2,11‐bis(diphenylphosphinomethyl)benzo[c]phenanthrene) have been prepared and assigned trigonal bipyramidal structures with apical phosphorus atoms from IR. and NMR. data.

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