𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Transition metal complexes of monohydroxamic acids

✍ Scribed by D.A. Brown; Dervilla McKeith (née Byrne); W.K. Glass

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
533 KB
Volume
35
Category
Article
ISSN
0020-1693

No coin nor oath required. For personal study only.

✦ Synopsis

Bioinorganic Chemistry Paper 5

Complexes of monohydroxamic acids and Fe(M)), Co(U), Ni(II) and Cu(II) are shown to involve chelation via the oxygen atoms of the donor &and. Spectral and magnetic properties of the complexes of Fe(III), Co(H), and Ni(II) indicate octahedral coordination with the latter two metal ions forming polymeric species. The monohydroxamic acid complexes show slightly larger 1ODq values than the corresponding aquo and acetylacetonato complexes.

Cu(II) forms a square planar complex probably with a d,.. ground state.

📜 SIMILAR VOLUMES

Transition metal complexes of monoyhydro
Transition metal complexes of monoyhydroxamic acids
✍ D.A. Brown; Devilla McKeith; W.K. Glass 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 63 KB

The publishers would like to point out that the following corrigenda are due in no way to organisational inefficiencies on their part but to the late arrival of the author's proof in the case of the corrigendum to Vol. 34 and to a postal strike in Ireland in the case of the corrigenda to Vol. 35.

Transition metal complexes with uronic a
Transition metal complexes with uronic acids
✍ D. Filipiuk; L. Fuks; M. Majdan 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 161 KB

FT-IR spectra of crystalline alginic acid and of its complexes formed by selected transition metal cations have been recorded, assigned and discussed in terms of structure of the investigated compounds.

The infrared spectra of monohydroxamic a
The infrared spectra of monohydroxamic acid complexes of copper, iron and nickel
✍ D.A. Brown; Dervilla McKeith; W.K. Glass 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 63 KB

The publishers would like to point out that the following corrigenda are due in no way to organisational inefficiencies on their part but to the late arrival of the author's proof in

The infrared spectra of monohydroxamic a
The infrared spectra of monohydroxamic acid complexes of copper, iron and nickel
✍ D.A. Brown; Dervilla McKeith (née Byrne); W.K. Glass 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 425 KB

A normal coordinate treatment of Cu(iK4HA)~. Fe(MAHA), and Ni(MAHA),, (MHA = N-methylhydroxamic acid) has been carried out, using a 1:l metal-ligand model and a Urey-Bradley force field. The methyl group was treated as a point mass. Very satisfactory agreements of observed and calculated inplane inf