𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The infrared spectra of monohydroxamic acid complexes of copper, iron and nickel

✍ Scribed by D.A. Brown; Dervilla McKeith (née Byrne); W.K. Glass

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
425 KB
Volume
35
Category
Article
ISSN
0020-1693

No coin nor oath required. For personal study only.

✦ Synopsis

A normal coordinate treatment of Cu(iK4HA)~. Fe(MAHA), and Ni(MAHA),, (MHA = N-methylhydroxamic acid) has been carried out, using a 1:l metal-ligand model and a Urey-Bradley force field. The methyl group was treated as a point mass. Very satisfactory agreements of observed and calculated inplane infrared frequencies were obtained for copper-(II) and iron( the metal-oxygen bonds are equivalent, haying force constants of ca. 1.08 mdyn/ A Delocalization does occur over the chelate system resulting in significant double bond character of the C-N bond, and to a lesser extent of the N-O bond.

📜 SIMILAR VOLUMES

The infrared spectra of monohydroxamic a
The infrared spectra of monohydroxamic acid complexes of copper, iron and nickel
✍ D.A. Brown; Dervilla McKeith; W.K. Glass 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 63 KB

The publishers would like to point out that the following corrigenda are due in no way to organisational inefficiencies on their part but to the late arrival of the author's proof in