Transition metal complexes of homoleptic polythia crowns
β Scribed by M. N. Bell; A. J. Blake; R. O. Gould; A. J. Holder; T. I. Hyde; A. J. Lavery; G. Reid; M. Schroder
- Publisher
- Springer Netherlands
- Year
- 1987
- Tongue
- English
- Weight
- 190 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0923-0750
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A solution of 1 a (0.1 g, 0.2 mmol) in hexane (10 mL) was very slowly evaporated to dryness under vacuum. Hexane (10 mL) was added to the residue, giving an orange precipitate corresponding to the dimer 2 a; the monomer 1 a remained in solution. The solution was filtered off and then retreated with
This review updates the electrochemical and structural aspects of homoleptic quinoidal (or pseudo-quinoidal) molecules coordinated to (single) transition metal ions. In fact, since 1,2-dioxolenes are redox-active molecules able to shuttle reversibly through the sequence quinone/hydroquinone/catechol