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Transition Metal Complexes of Boron

✍ Scribed by Holger Braunschweig


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
401 KB
Volume
37
Category
Article
ISSN
0044-8249

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10 ml, and chromatographed on a silica gel column (Merck 0.05 to 0.2 mm; column dimensions 40 x 2 cm) at 0Β°C with hexane/benzene (4 : 1). The yellow zone is collected, the solvent removed in a high vacuum, and the residue recrystallized twice from n-pentane : pale yellow needles, m. p. 45 "C ; yield

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from a benzene solution at room temperature. 1 H NMR (400.1 MHz, C 6 D 6 ): d = 2.71Γ€2.60 (m, 6 H, Cy), 2.23Γ€2.15 (m, 12 H, Cy), 1.81Γ€1.20 (m, 48 H, Cy); 11 B{ 1 H} NMR (128.4 MHz, C 6 D 6 ): d = 30 ppm; 13 C{ 1 H} NMR (100.6 MHz, C 6 D 6 ): d = 35.8 (vt, N =j 1 J P-C + 3 J P-C j= 28 Hz, C 1 Cy), 30