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Transition metal complexes in organic synthesis, part 50. Asymmetric catalytic complexation of 1-methoxycyclohexa-1,3-diene by the tricarbonyliron fragment using amino acid-derived 1-azabuta-1,3-dienes

✍ Scribed by Hans-Joachim Knölker; Daniela Herzberg

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 145 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00548-1

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✦ Synopsis

L-Amino acid esters as chiral auxiliaries in the asymmetric complexation of 1-methoxycyclohexa-l,3-diene with pentacarbonyliron afford the R-enantiomer of the corresponding planar chiral tricarbonylimn complex in up to 24% ee.

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