Transition metal-diene complexes in organic synthesis, part 26.1 synthesis of enantiopure (η4-1-Aza-1,3-butadiene)tricarbonyliron complexes
✍ Scribed by Hans-Joachim Knölker; Gerhard Baum; Peter Gonser
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 278 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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The (η 4 -1-azabuta-1,3-diene)tricarbonyliron complexes 10 spectroscopy, as well as X-ray crystallography of 10b, 10c, and 10l. Using variable temperature 13 C-NMR spectroscopy are easily prepared in high yield by condensation of the corresponding arylamines 7 with the cinnamaldehydes 8 and the flux