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Transition metal complexes in organic synthesis. Part 46. Synthesis of 5-arylmethyl-substituted tricarbonyl(1-4-η-cyclohexa-1,3-diene)iron complexes

✍ Scribed by Prof. Dr. Hans-Joachim Knölker; Michael Graf; Ulrik Mangei

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
666 KB
Volume
340
Category
Article
ISSN
1615-4150

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Synthesis of 4-substituted-tricarbonyl(η
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The reaction of neutral 1-substituted-tricarbonyl(q4-4-methoxycyclohexa-l,3-diene)iron complexes 3 with thallium(III) trifluoroacetate in alcoholic solution leads to the corresponding new 4-substituted-tricarbonyl(q 4cyclohexa-2,4-dien-l-one)iron complexes 4. A mechanism for this reaction is propose