We wish to report the first example of a zinc-catalyzed rearrangement of the bicycle [P.l.O]pentane ring system. Namely, the rearrangement of I-Phenylbicyclo[2.1.O]pentane(b) with a catalytic amount of zinc iodide in benzene (2 hr, 60') to give as the sole product 3-phenylcyclopentene(2a).
โฆ LIBER โฆ
Transition Metal Complex Promoted Rearrangements. Bicyclo[2.1.0]pentane and 1-Carbomethoxybicyclo[2.1.0]pentane
โ Scribed by Gassman, Paul; Atkins, Thomas; Lumb, J
- Book ID
- 126254805
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 710 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0002-7863
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