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Transition metal catalyzed oxidations. 12.α-chlorination of silylenol ethers with tert-butyl hydroperoxide and TiCl2(OiPr)2

✍ Scribed by Karsten Krohn; Klaus Steingröver; Ingeborg Vinke


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
30 KB
Volume
341
Category
Article
ISSN
1615-4150

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Transition Metal-Catalyzed Oxidations. 1
✍ Karsten Krohn; Hagen Rieger; Klaus Steingröver; Ingeorg Vinke 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 28 KB 👁 1 views

Selectivity is a major goal in modern synthetic chemistry . This goal is relatively difficult to achieve in some electrophilic aromatic substitutions especially in the halogenation of phenols. Mixtures of ortho-and para-substitution products are usually formed which are often difficult to separate.