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ChemInform Abstract: Transition Metal-Catalyzed Oxidations. Part 12. α-Chlorination of Silylenol Ethers with tert-Butyl Hydroperoxide and TiCl2(OiPr)2.

✍ Scribed by Karsten Krohn; Klaus Steingroever; Ingeborg Vinke


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Transition Metal-Catalyzed Oxidations. 1
✍ Karsten Krohn; Hagen Rieger; Klaus Steingröver; Ingeorg Vinke 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 28 KB 👁 2 views

Selectivity is a major goal in modern synthetic chemistry . This goal is relatively difficult to achieve in some electrophilic aromatic substitutions especially in the halogenation of phenols. Mixtures of ortho-and para-substitution products are usually formed which are often difficult to separate.