The title rearrangement proceeds in dichloromethane the presence of the catalyst prepared 7:n situ to give tertiary good yields. Other rearrangements of sec. +tert. or sec. +sec examined.
β¦ LIBER β¦
Transition-metal catalyzed oxidation of alcohols to aldehydes and ketones by means of Me3SiOOSiMe3
β Scribed by Shigekazu Kanemoto; Koichiro Oshima; Seijiro Matsubara; Kazuhiko Takai; Hitosi Nozaki
- Book ID
- 104217328
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 223 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Pyridinium dichromate-Me3SiOOSiMe3 system has been found to be effective for the oxidation of alcohols to the corresponding carbonyl compounds.
Selective oxidation of primary alcohols in the presence of secondary ones with RuC12(PPh3)3-Me3Si00SiMe3 is also described.
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