Isomerization of primary allylic alcohols to tertiary ones by means of Me3SiOOSiMe3-VO(acac)2 catalyst

✍ Scribed by Seijiro Matsubara; Kazuhiko Takai; Hitosi Nozaki

• Book ID: 104226591
• Publisher: Elsevier Science
• Year: 1983
• Tongue: French
• Weight: 226 KB
• Volume: 24
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)94523-4

✦ Synopsis

The title rearrangement proceeds in dichloromethane the presence of the catalyst prepared 7:n situ to give tertiary good yields.

Other rearrangements of sec. +tert. or sec. +sec examined.