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Transition metal-catalyzed diastereoselective aldol reactions of prochiral ketones with methyl isocyanoacetate

โœ Scribed by Vadim A. Soloshonok; Alexey D. Kacharov; Dimitry V. Avilov; Tamio Hayashi

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
279 KB
Volume
37
Category
Article
ISSN
0040-4039

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Transition Metal/Base-Catalyzed Aldol Reactions of Isocyanoacetic Acid Derivatives with Prochiral Ketones, a Straightforward Approach to Stereochemically Defined ฮฒ,ฮฒ-Disubstituted-ฮฒ-hydroxy-. alpha.amino Acids. Scope and Limitations. -Methyl isocyanoacetate (II) undergoes aldol type reactions with