## Abstract The kinetics of isomerization of butenes by boron trifluoride with acetic acid or methanol as cocatalysts have been reβexamined. The results, over a wide concentration range, and at temperatures from β20 to +20Β°C, are consistent with previous data, but it is shown that the previously su
β¦ LIBER β¦
Transition metal catalysis of olefin isomerizations
β Scribed by Alfred B. Anderson
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 189 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The zbili!y of transition mctti atoms and clusters to catalyze olctin isomerizstions is traced to metal d orbital stabili-73tion of the olcfin transition state 71 orbita!.
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## Abstract **Diaminations are a girl's best friend**: New reactions in the field of transitionβmetalβcatalyzed diamination of olefins provide a powerful tool for the elaboration of more complex molecules bearing the 1,2βdiamine moiety. An overview of these methods, including asymmetric versions, i