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Transition dipole-solvent interaction in photoionization

✍ Scribed by Paul Delahay; Andrew Dziedzic

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
405 KB
Volume
132
Category
Article
ISSN
0009-2614

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✦ Synopsis

The interaction between solvent molecules and transition dipoles results in a measurable non-equilibrium electronic contribution to the energetics of photoionization in the case of significant dielectric dispersion of the solvent at the prevailing photon energy. Earlier theoretical work on the resulting dispersion shift is justified on the basis of transition dipole-solvent interaction. Additional experimental evidence is presented.

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✍ W.Ronald Fawcett πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 785 KB

Data for AH,, the enthalpy of activation determining the temperature dependence of the Debye relaxation time have been collected and compared for polar aprotic solvents of lower molecular weight. It is shown that the variation in this quantity with solvent can be largely attributed to a correspondin