The interaction between solvent molecules and transition dipoles results in a measurable non-equilibrium electronic contribution to the energetics of photoionization in the case of significant dielectric dispersion of the solvent at the prevailing photon energy. Earlier theoretical work on the resul
Transition dipole-solvent interaction in optical electron transfer
β Scribed by Paul Delahay; Andrew Dziedzic
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 845 KB
- Volume
- 228
- Category
- Article
- ISSN
- 0022-0728
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## Abstract The contribution of longβrange forces to the observed rates of __V__ β __V__ energy transfer processes has been studied. The theoretical model uses the first order perturbation approximation to generate a probability function, with the dipoleβdipole perturbing potential as given by Marg