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Transient absorption, lifetime and relaxation of C60 in the triplet state

✍ Scribed by Yoshizumi Kajii; Takashi Nakagawa; Shinzo Suzuki; Yohji Achiba; Kinichi Obi; Kazuhiko Shibuya


Book ID
107735265
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
438 KB
Volume
181
Category
Article
ISSN
0009-2614

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Absorption spectrum, lifetime and reacti
✍ J.C. Scaiano; D. Weir πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 456 KB

The first excited triplet state of dimesitylcarbene has been generated in solution at room temperature. It has a lifetime of 60 ns and shows fluorescence with A mp~ = 501 nm and absorption with A,,. = 360 nm. This species is quenched by oxygen and carbon tetrachloride with rate constants of (4.4kO.8