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Transformylation in the Synthesis of Adenine-8-C 14

✍ Scribed by Abrams, Richard; Clark, Leon


Book ID
126873897
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
265 KB
Volume
73
Category
Article
ISSN
0002-7863

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## Abstract The synthesis of [^14^C] PMEA (3) was achieved by coupling the sodium salt of 8‐[^14^C]adenine (1) with 2‐(diisopropyl‐phosphonymethoxy) ethanol methanesulfonate in N,N‐dimethylformamide at 100Β°C to provide the diisopropyl ester (2). Deesterification with bromotrimethylsilane in acetoni