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Transformation of a Spherical Supramolecular Dendrimer into a Pyramidal Columnar Supramolecular Dendrimer Mediated by the Fluorophobic Effect

✍ Scribed by Virgil Percec; Martin Glodde; Gary Johansson; Venkatachalapathy S. K. Balagurusamy; Paul A. Heiney


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
300 KB
Volume
115
Category
Article
ISSN
0044-8249

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Cover Picture: Transformation of a Spher
✍ Virgil Percec; Martin Glodde; Gary Johansson; Venkatachalapathy S. K. Balagurusa πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 21 KB πŸ‘ 2 views

**The mode of the self‐assembly** of **(3,4,5)**^**2**^**G2‐CO**~**2**~**Me** monodendrons changes from a spherical to a pyramidal supramolecular dendrimer upon replacement of the aliphatic chains by partially fluorinated chains. This metamorphosis was verified with a combination of small‐ and wide‐