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Titelbild: Transformation of a Spherical Supramolecular Dendrimer into a Pyramidal Columnar Supramolecular Dendrimer Mediated by the Fluorophobic Effect (Angew. Chem. 36/2003)

✍ Scribed by Virgil Percec; Martin Glodde; Gary Johansson; Venkatachalapathy S. K. Balagurusamy; Paul A. Heiney

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 22 KB
Volume: 115
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200390604

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Transformation of a Spherical Supramolecular Dendrimer into a Pyramidal Columnar Supramolecular Dendrimer Mediated by the Fluorophobic Effect

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Cover Picture: Transformation of a Spher

Cover Picture: Transformation of a Spherical Supramolecular Dendrimer into a Pyramidal Columnar Supramolecular Dendrimer Mediated by the Fluorophobic Effect (Angew. Chem. Int. Ed. 36/2003)

✍ Virgil Percec; Martin Glodde; Gary Johansson; Venkatachalapathy S. K. Balagurusa 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 21 KB 👁 2 views

**The mode of the self‐assembly** of **(3,4,5)**^**2**^**G2‐CO**~**2**~**Me** monodendrons changes from a spherical to a pyramidal supramolecular dendrimer upon replacement of the aliphatic chains by partially fluorinated chains. This metamorphosis was verified with a combination of small‐ and wide‐