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Transfer of oxygen from a 4a-hydroperoxyflavin anion to a phenolate ion. A flavin-catalyzed dioxygenation reaction

✍ Scribed by Kemal, Cemal; Bruice, Thomas C.

Book ID
126941197
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
585 KB
Volume
101
Category
Article
ISSN
0002-7863

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Identifying the Intermediate in the Diox
Identifying the Intermediate in the Dioxygen Transfer from 4a-Hydroperoxyflavin Anion to Phenolate and Indole Anions
✍ Ya-Jun Zheng; Thomas C. Bruice πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 204 KB

Semiempirical and ab initio molecular orbital methods are used to identify the plausible intermediate involved in dioxygen transfer from 4a-hydroperoxyflavin anion to phenolate and indole anions. According to the present study, both 4,4a-dioxetane and 4a,10-dioxetane derived from 4a-hydroperoxyflavi