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Dioxygen transfer from 4a-hydroperoxyflavin anion. 3. Oxygen transfer to the 3-position of substituted indoles

โœ Scribed by Muto, Shigeaki; Bruice, Thomas C.

Book ID
126859587
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
686 KB
Volume
102
Category
Article
ISSN
0002-7863

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Identifying the Intermediate in the Diox
Identifying the Intermediate in the Dioxygen Transfer from 4a-Hydroperoxyflavin Anion to Phenolate and Indole Anions
โœ Ya-Jun Zheng; Thomas C. Bruice ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 204 KB

Semiempirical and ab initio molecular orbital methods are used to identify the plausible intermediate involved in dioxygen transfer from 4a-hydroperoxyflavin anion to phenolate and indole anions. According to the present study, both 4,4a-dioxetane and 4a,10-dioxetane derived from 4a-hydroperoxyflavi