Transfer of Carbyne Ligands from Chromium to Cobalt
✍ Scribed by Prof. Dr. Ernst Otto Fischer; Dipl.-Chem. Albrecht Däweritz
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- English
- Weight
- 248 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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Compound ( 1 ) (0.68g, 4mmol) is dissolved under N2 in anhydrous tetrahydrofuran (50 ml). To this solution, cooled to -113"C, is added dropwise a solution of tert-butyllithium in n-pentane (3ml,5.1 mmol; ca. 1.7 M solution). After 15min the olefin or carbonyl compound (8mmol) is addedC6]. The soluti
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