Intramolecular Carbyne–Isocyanide Coupli
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Alexander C. Filippou; Bernhard Lungwitz; Gabriele Kociok-Köhn
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Article
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1999
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John Wiley and Sons
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English
⚖ 345 KB
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Oxidative decarbonylation of Cp\*(CO) 2 WϵCNEt 2 (1) with 16e carbene complex Cp\*(Cl) 3 W=C(H)NEt 2 (6) after elimination of P(OMe) 3 . Complex 5 was obtained from the PhICl 2 affords the aminocarbyne complex cis-Cp\* (Cl) 2 (CO)WϵCNEt 2 (2), which reacts with tBuNC to give the CO ligand-exchange r