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Metal-Centered Coupling of Two Carbyne Ligands To Form an Alkyne Ligand

✍ Scribed by Dr. Alexander Constantin Filippou; Dr. Walter Grünleitner; Dipl.-Chem. Christian Völkl; Dipl.-Chem. Paul Kiprof


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
341 KB
Volume
30
Category
Article
ISSN
0044-8249

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Intramolecular Carbyne–Isocyanide Coupli
✍ Alexander C. Filippou; Bernhard Lungwitz; Gabriele Kociok-Köhn 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 345 KB 👁 1 views

Oxidative decarbonylation of Cp\*(CO) 2 WϵCNEt 2 (1) with 16e carbene complex Cp\*(Cl) 3 W=C(H)NEt 2 (6) after elimination of P(OMe) 3 . Complex 5 was obtained from the PhICl 2 affords the aminocarbyne complex cis-Cp\* (Cl) 2 (CO)WϵCNEt 2 (2), which reacts with tBuNC to give the CO ligand-exchange r