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Transesterification/Acylation Reactions Catalyzed by Molecular Catalysts

✍ Scribed by Gabriela A. Grasa; Rohit Singh; Steven P. Nolan

Publisher
John Wiley and Sons
Year
2004
Weight
51 KB
Volume
35
Category
Article
ISSN
0931-7597

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Enantioselective lipase-catalyzed reacti
Enantioselective lipase-catalyzed reactions of methyl pipecolinate: transesterification and N-acylation
✍ Arto Liljeblad; Jutta Lindborg; Anu Kanerva; Johanna Katajisto; Liisa T. Kanerva πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 108 KB

The present research introduces the highly (S)-selective (E>>100) acylation at the secondary ring nitrogen of methyl pipecolinate as a novel resolution method with Candida antarctica lipase A. Catalysis by lipase B leads to reactions at the methyl ester function of the substrate in an almost non-ena