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Transannular Interactions in Polycyclic Hydrocarbons. The System of Cage-Shaped Hexacyclo[6.6.0.02,6.03,13.04,11.05,9]tetradecane Derivatives

✍ Scribed by Chow, Tahsin J.; Wei, Chin-Chuan; Wu, Tung-Kung; Martin, Hans-Dieter; Mayer, Bernhard


Book ID
126786332
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
725 KB
Volume
60
Category
Article
ISSN
0022-3263

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Synthesis of rod-shaped compounds: bis(7
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## 6 13 II 59 1014 The rod-shaped hydrocarbon molecules 1 and 2 are synthesized from heptacyclo[6.6.0.02' .03' .04' .0, .0 ' ]tetradecane (HCTD) derivatives according to Barton's procedure, where the structures of 1 and the corresponding diketone of 2 belong to D2h and D~ symmetries, respectively