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Transacylation. Biomimetic synthesis of esters of acetic acid

✍ Scribed by Ivan T. Devedjiev; Vesselin G. Ganev

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 540 KB
Volume: 17
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20216

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✦ Synopsis

Abstract

By mixing of β‐hydroxypropyl phosphate and acetic acid in ethanol solution, ethyl acetate is produced. As found, acetyl phosphate is first formed, then it reacts with the solvent to give the final ethyl acetate product. By similar procedures, acetates of methanol, n‐propanol, and n‐butanol are also produced. Propylene oxide serves as a condensing agent. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:350–352, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20216

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