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Biomimetic synthesis of esters of natural amino acids

✍ Scribed by Ivan T. Devedjiev; Stanislav G. Bairyamov; Vladimira S. Videva

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 148 KB
Volume: 19
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20427

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✦ Synopsis

Abstract

A method for the synthesis of Gly, Ala, Phe, and Thr esters is proposed and considered as being a stage of possible biomimetic synthesis of peptides. The methyl esters of the said amino acids are obtained via intervention of 2‐hydroxypropyl phosphonate. The resulting aminoacyl phosphonates reacts with methanol to produce the amino acid methyl esters, with the release of phosphoric acid. The reaction is carried out at room temperature in water. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:252–255, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20427

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