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Trans Influence of Phosphines on Dimer-Monomer Interconversion of 2-Pyridinethiolate Complexes: Structures of [Pd(.mu.-.eta.2-pyS-N,S)Cl(L)]2 (L = PMe2Ph, PMePh2) and Pd(.eta.2-pyS)Cl(PPh3)

โœ Scribed by Gupta, Mukta; Cramer, Roger E.; Ho, Kachum; Pettersen, Christina; Mishina, Staffany; Belli, Jack; Jensen, Craig M.


Book ID
126223006
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
721 KB
Volume
34
Category
Article
ISSN
0020-1669

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## Abstract A series of monoโ€ and disubstituted diiron complexes [(ฮผโ€pdt)Fe~2~(CO)~5~L] [pdt = 1,3โ€propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(ฮผโ€pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Feโ€only hydrogenaseโ€activeโ€site mo