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Trans effects in the Heck reaction—A model study

✍ Scribed by Carina Bäcktorp; Per-Ola Norrby


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
299 KB
Volume
328
Category
Article
ISSN
1381-1169

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Theoretical studies of the pathway in the Heck reaction between ethen¢ and a methyl el~.rOl~ile at IPd(H2ACH2AH2XCH3)ffI2C=CH2)I + (A = P, N) reveal intermediates with an agostic H which is the one p~ferential .ly transferred to base.