The Heck olefination reaction; A DFT stu
✍
Robert J. Deeth; Andrew Smith; King Kuok (Mimi) Hii; John M. Brown
📂
Article
📅
1998
🏛
Elsevier Science
🌐
French
⚖ 253 KB
Theoretical studies of the pathway in the Heck reaction between ethen¢ and a methyl el~.rOl~ile at IPd(H2ACH2AH2XCH3)ffI2C=CH2)I + (A = P, N) reveal intermediates with an agostic H which is the one p~ferential .ly transferred to base.