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The Heck olefination reaction; A DFT study of the elimination pathway

✍ Scribed by Robert J. Deeth; Andrew Smith; King Kuok (Mimi) Hii; John M. Brown

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
253 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Theoretical studies of the pathway in the Heck reaction between ethenΒ’ and a methyl el~.rOl~ile at IPd(H2ACH2AH2XCH3)ffI2C=CH2)I + (A = P, N) reveal intermediates with an agostic H which is the one p~ferential .ly transferred to base.

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