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Trans-effect in the kinetics of reactions of mixed Cu(II) acetate solvates withN-methyloctaethylporphine

โœ Scribed by O. V. Toldina; D. B. Berezin; P. A. Shatunov; B. D. Berezin


Book ID
111457909
Publisher
SP MAIK Nauka/Interperiodica
Year
2006
Tongue
English
Weight
224 KB
Volume
32
Category
Article
ISSN
1070-3284

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The rate of the solvent substitution reaction, CoCl 3 S ร€ +Cl ร€ YCoCl 4 2ร€ +S (S-solvent) has been studied by means of stopped flow spectrophotometry in dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF), and the rate constant k f , and the activation enthalpy D f H p and entropy D f S p have