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Investigations on the reaction kinetics and the catalytic effect of Cu(II) and V(V) in the oxidation of cyclohexanol by nitric acid

✍ Scribed by Y. Qu; C. Fang; M. Duan; J. Wang

Book ID
121857661
Publisher
Springer-Verlag
Year
2014
Tongue
English
Weight
752 KB
Volume
112
Category
Article
ISSN
1878-5190

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Preparation of adipic acid by oxidation
Preparation of adipic acid by oxidation of cyclohexanol and cyclohexanone with nitric acid: Part II. Reaction kinetics of the decomposition of 6-hydroxyimino-6-nitro hexanoic acid
✍ W. J. van Asselt; D. W. van Krevelen πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 328 KB

## Abstract The stablest intermediate product formed in the oxidation of cyclohexanol and cyclohexanone is 6‐hydroxyimino‐6‐nitro hexanoic acid (nitrolic acid). In the temperature range investigated it yields over 90% of adipic acid and N~2~O. In addition, a small amount of a still unidentified by‐