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The role of vanadium(V) in the oxidation of cyclohexanol to adipic acid by nitric acid

✍ Scribed by Smith, J. R. Lindsay; Richards, D. I.; Thomas, C. B.; Whittaker, M.

Book ID
120006995
Publisher
Royal Society of Chemistry
Year
1985
Tongue
English
Weight
747 KB
Volume
10
Category
Article
ISSN
1472-779X

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πŸ“œ SIMILAR VOLUMES

Preparation of adipic acid by oxidation
Preparation of adipic acid by oxidation of cyclohexanol and cyclohexanone with nitric acid: Part I. Reaction mechanism
✍ W. J. van Asselt; D. W. van Krevelen πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 662 KB

## Abstract The oxidation of cyclohexanol with nitric acid to adipic acid proceeds via two stable intermediates known from the literature^1^ viz. 6‐hydroxyimino‐6‐nitro hexanoic acid and the hemihydrate of 1,2‐cyclohexanedione, two substances forming beside each other in a given ratio. This ratio c

Preparation of adipic acid by oxidation
Preparation of adipic acid by oxidation of cyclohexanol and cyclohexanone with nitric acid: Part II. Reaction kinetics of the decomposition of 6-hydroxyimino-6-nitro hexanoic acid
✍ W. J. van Asselt; D. W. van Krevelen πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 328 KB

## Abstract The stablest intermediate product formed in the oxidation of cyclohexanol and cyclohexanone is 6‐hydroxyimino‐6‐nitro hexanoic acid (nitrolic acid). In the temperature range investigated it yields over 90% of adipic acid and N~2~O. In addition, a small amount of a still unidentified by‐