trans-Dichlorobis(di-n-propyl sulfoxide)platinum(II)
✍ Scribed by Melanson, R. ;Rochon, F. D.
- Book ID
- 114505700
- Publisher
- International Union of Crystallography
- Year
- 1988
- Tongue
- English
- Weight
- 322 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
In the title centrosymmetric complex, trans-[PtCl 2 (C 6 H 10 N 2 ) 2 ], the Pt II centre is coordinated by two piperidine-1-carbonitrile ligands and two chloro ligands, resulting in a typical squareplanar geometry. The C-N distance between the nitrile and piperidine group [1.306 (4) A ˚] clearly in
The title compound, [Pt 2 Cl 2 (C 6 H 5 ) 2 (C 2 H 6 OS) 2 ] or [Pt("-Cl)Ph(dmso)] 2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is c