trans-Di-μ-chloro-bis[chloro(tributylphosphine)palladium]
✍ Scribed by Chaloner, P. A. ;Dewa, S. Z. ;Hitchcock, P. B.
- Book ID
- 114511575
- Publisher
- International Union of Crystallography
- Year
- 1995
- Tongue
- English
- Weight
- 189 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 220 K Mean '(C±C) = 0.005 A Ê R factor = 0.034 wR factor = 0.089 Data-to-parameter ratio = 17.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Pd 2 Cl 2 ("-C 6 H 5 Se) 2 (C 18 H 15 P) 2 ], crystallizes as a centrosymmetric phenylselenolato-bridged dinuclear palladium complex. The Pd atom shows a slightly distorted square-planar coordination geometry, with the PdÐSe distance trans to the terminal Cl À ligand at 2.4174 (