In the title compound, [PdCl 2 {(5-C 4 H 4 N)(5-C 5 H 5 )Fe} 2 ], the Pd II atom lies on an inversion center in a slightly distorted square-planar arrangement of cis Cl and N ligands. The azaferrocene ligands display a typical sandwich structure with practically parallel Cp and pyrrolyl rings. Weak
trans-Bis(benzylamine)dichloropalladium(II)
✍ Scribed by Sui-Seng, Christine ;Zargarian, Davit
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 156 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
PdCl 2 (C 7 H 9 N) 2 ] or trans-[PdCl 2 (NH 2 CH 2 Ph) 2 ], lies on a twofold axis. It has a distorted square-planar coordination environment formed by two benzylamine and two Cl À ligands. The symmetry-unique cis angles at the Pd atom are 86. 25 (11) and 93.75 (11) .
📜 SIMILAR VOLUMES
The structure of the title compound, [PdCl 2 (C 10 H 10 N 2 ) 2 ], has the palladium center situated on a center of inversion. The imidazole group is twisted from the square coordination plane with a C-N-Pd-Cl torsion angle of 31.93 (12) ; this is different from the angle reported in closely related
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.009 A Ê Some non-H atoms missing Disorder in main residue R factor = 0.046 wR factor = 0.120 Data-to-parameter ratio = 17.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.