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trans-Bis(4-amino­pyridine-κN)bis­(succinimidato-κN)copper(II) dihydrate

✍ Scribed by Akitsu, Takashiro ;Einaga, Yasuaki

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
135 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu(C 4 H 4 NO 2 ) 2 (C 5 H 6 N 2 ) 2 ]Á2H 2 O, has its metal atom in a square-planar trans-[CuN 4 ] coordination environment; the Cu II atom lies on a center of symmetry. Both succinimidate and 4-aminopyridine ligands behave as monodentate ligands, which coordinate through deprotonated imidate and pyridine (not amino) N atoms, respectively. The 4-aminopyridine is the first ligand in such Cu II complexes containing two different N atoms to take potentially different coordination modes. metal-organic papers Acta Cryst. (2006). E62, m625-m627 Akitsu and Einaga [Cu(C 4 H 4 NO 2 ) 2 (C 5 H 6 N 2 ) 2 ].2H 2 O m627

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