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Trans-annular interactions in morpholines: A photoelectron spectroscopic study

✍ Scribed by Igor Novak; Branka Kovaĉ

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
245 KB
Volume
6
Category
Article
ISSN
1042-7163

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✦ Synopsis

The He I and He 11 photoelectron spectra of 4-methvlmorpholine, 4-rnorpholinecarbonitrile, and 4-morpholinepropionitrile have been measured. The electronic structure and heteroatom lone pair interactions, in particular, were analyzed with the aid of H e l l / HeI intensity variations, comparison with the spectra of related compounds, and AM1 semiempirical calculations. W e present an example of combined inductive and resonance interactions operating in the morpholine ring system.

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