trans-Addition of Two Carbon Substituents across a Benzene Double Bond in [(η6-Benzene)Mo(CO)3]

✍ Scribed by E. Peter Kündig; Charles-H. Fabritius; Gabriele Grossheimann; Fabrice Robvieux; Patrick Romanens; Gérald Bernardinelli

• Book ID: 101375004
• Publisher: John Wiley and Sons
• Year: 2002
• Tongue: English
• Weight: 158 KB
• Volume: 114
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/1521-3757(20021202)114:23<4759::aid-ange4759>3.0.co;2-2

✦ Synopsis

The benzene ligand in 1 is susceptible to substitution by THF at ambient temperature but stable solutions can be prepared by maintaining low temperatures at all times. Scheme 1. Reaction sequence for formation of 7 a. In situ IR spectroscopic measurements were carried out under conditions designed to optimize the spectra obtained.