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trans-Addition of Two Carbon Substituents across a Benzene Double Bond in [(η6-Benzene)Mo(CO)3]

✍ Scribed by E. Peter Kündig; Charles-H. Fabritius; Gabriele Grossheimann; Fabrice Robvieux; Patrick Romanens; Gérald Bernardinelli

Book ID
101365923
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
157 KB
Volume
41
Category
Article
ISSN
0044-8249

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trans-Addition of Two Carbon Substituent
trans-Addition of Two Carbon Substituents across a Benzene Double Bond in [(η6-Benzene)Mo(CO)3]
✍ E. Peter Kündig; Charles-H. Fabritius; Gabriele Grossheimann; Fabrice Robvieux; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB

The benzene ligand in 1 is susceptible to substitution by THF at ambient temperature but stable solutions can be prepared by maintaining low temperatures at all times. Scheme 1. Reaction sequence for formation of 7 a. In situ IR spectroscopic measurements were carried out under conditions designed t